稀土离子在薄层色谱过程中的行为及展开剂的研究

本文从马丁方程出发对薄层吸附色谱过程中稀土离子的行为机理作了探索,在实验基础上研究五个展开体系对稀土元素 R_M 的影响,论证了展开剂各组分之间的竞争效应,协萃效应及反协萃效应对稀土元素 R_M 世和相邻稀土元素ΔR_M 的影响趋势,同时对如何选择展开剂最佳条件进行了讨论,对目前所用的一些方法作了比较和研究。     

梯度洗脱高效离子交换色谱法分离测定独居石中单一稀土元素的研究

本文对用梯度洗脱高效离子交换色谱分离单一稀土元素作了研究。在国产仪器及填料的基础上,提出以α-羟基异丁酸(α-HIBA)为洗脱剂,偶氮胂Ⅲ作为柱后显色剂分离并定量测定独居石中单一稀土元素含量的方法,研究了梯度中强溶剂 P(s)、弱溶剂 P(w)和梯度洗脱曲线形状 N 对分离的影响以及镧、铈、镨、钕、钐、铕、钇的分离测定条件,并在最佳实验条件下,分析了独居石样品,各元素的回收率均在95.3%～104.6%之间。     

薄层层析法分离重稀土元素

本文研究的薄层层析法分离重稀土元素的固定相为硅胶H/硝酸铵/CMC/H_2O(W/W33:4:1:110),展开剂为:1.二-2-乙基己基磷酸-异丙醚-乙醚-硝酸,2.单-2-乙基已基磷酸-异丙醚-乙醚-硝酸。本文测定了各重稀土元素的R_f值,研究了改变展开剂中各组分比例对各稀土元素色谱行为及分离效果的影响。当二-2-乙基已基磷酸-异丙醚-乙醚-硝酸体积比为1:10:6:1.1,单2-乙基己基磷酸-异丙醚-乙醚-硝酸体积比为1:8:8:1.1时,各相邻重稀土元素间均能表现出较明显的R_f值差异。分离上述稀土标准混合液,各元素的分离情况可达到定量测定要求,结果令人满意。     

深部储层动力学刍议

随着非线性科学的发展及其在地学中的应用,人们逐渐认识到深中储层并非是一封闭、孤立的系统,而是一典型的耗散系统,其含油气性受深部壳幔结构控制。借助非线性动力学思想,尝试提出“深部储层动力学”这一全新的概念及它的基本研究内容和解决问题的方法。     

保鲜剂对切花百合的保鲜效果和生理作用

本文研究了不同保鲜剂配方对切花百合品种“阿卡普克”（Acapulco）的保鲜效果，主要测定了切花鲜重、cAT活性、花蕾长度、叶绿素。结果表明，D配方（30g／LS＋400mg／L8-HQC＋200mg／LGA）对延缓切花百合衰老的效果最佳。     

深切悼念伟大的科学家陈省身院士

数学是科学之母。难忘的中华人民共和国南开数学研究所举行的国际微分几何与整体分析会议，陈省身院士91岁在国际数学家大会开幕式上发表重要讲话，为实现把中国建成数学大国而奋斗了二十多年。深切悼念伟大的科学家陈省身院士。     

Secondary instabilities of linearly heated falling films

Secondary instabilities of linearly heated failing films are studied through three steps. Firstly, the analysis of the primary linear instability on Miladinova's long wave equation of the linearly heated film is performed. Secondly, the similar Landau equation is derived through weak nonlinear theory, and a two-dimensional nonlinear saturation solution of primary instability is obtained within the weak nonlinear domain. Thirdly, the secondary (three-dimensional) instability of the two-dimensional wave is studied by the Floquet theorem.Our secondary instability analysis shows that the Marangoni number has destabilization effect on the secondary instability.     

Seasonal transition and its boundary layer characteristics in Anduo area of Tibetan Plateau

Using the data, especially the GPS rawinsode data, observed in Anduo area of the Tibetan Plateau during the intensive observation period of GAME/Tibet in 1998, the transition from the dry to the rainy season along with their boundary layer characteristics is analyzed comprehensively. The result shows that the formation of the rainy season in Anduo area is related closely to the general atmospheric circulation. The westerly belt moving north and the southeast damp current are basic conditions for development of the rainy season in Anduo area. In the dry season, the air is drier, air temperature higher, and the atmospheric boundary layer is strongly developed to cause its maximum height to reach about 3550 m. Moreover the sensible heat flux is dominant, and the latent heat flux is small in the interaction of land-atmosphere energy exchange, and a reverse humidity phenomenon occurs frequently. In the rainy season, the air is damper, air temperature lower, and the ABL height, with maximum of only about 2300 m, is lower. And the sensible heat flux becomes much smaller, the latent heat flux much larger in the interaction of land-atmosphere energy exchange. The reverse humidity phenomenon disappears.     

状态变量控制理论在区域经济政策调控中的应用

针对区域经济政策被控对象大惯性、大滞后的特点,该文结合现代控制理论,提出了基于状态变量控制理论的区域经济政策调控的全评估设计方法,即采用状态反馈来补偿政策被控对象的滞后和惯性,使得区域经济政策被控对象具有良好的动态响应特性,具备优良的调控性能。给出了状态反馈系数矩阵和政府制定的区域经济政策执行评估状态增益矩阵。该全评估方法可为政府制定经济政策提供决策参考,并为政策执行效果的整体后评价和经验总结提供科学的依据。     

遗传算法在系统辨识中的应用

对遗传算法的机理和实现步骤进行了介绍,综述了遗传算法在系统辨识中的应用.针对不同的辨识模型,讨论了遗传算法不同的应用形式,研究了遗传算法结合神经网络技术在系统辨识中的应用,最后探讨了遗传算法在系统辨识中的研究方向.